軽元素における特異な超伝導の解明(Unlocking unusual superconductivity in a lightweight element)

2026-04-13 ペンシルベニア州立大学(Penn State)

米国のペンシルベニア州立大学の研究チームは、軽元素を用いた新しいタイプの超伝導現象を解明した。従来の超伝導体は重元素に依存する場合が多いが、本研究では軽元素系材料においても特異な電子相互作用により超伝導が発現することを示した。特に電子構造や結晶構造の特異性が重要な役割を果たし、従来理論では説明が難しい振る舞いが観測された。これにより、超伝導メカニズムの理解が拡張され、新材料設計やエネルギー効率の高い電力伝送技術への応用が期待される。軽量かつ高性能な次世代超伝導材料開発に向けた重要な知見である。

軽元素における特異な超伝導の解明(Unlocking unusual superconductivity in a lightweight element)

Penn State MRSEC researchers have uncovered unusual superconductivity in a lightweight element gallium sandwich structure. Left: Cross-sectional scanning transmission electron microscopy image of a three-atomic-layer gallium film sandwiched between graphene and a silicon carbide substrate. Right: Schematic of Ising-type superconductivity in this gallium layer. Credit: Chang Laboratory / Penn State. Creative Commons

<関連情報>

閉じ込められたガリウム層における軌道混成によって誘起されるイジング型超伝導 Orbital-hybridization-induced Ising-type superconductivity in a confined gallium layer

Hemian Yi,Yunzhe Liu,Chengye Dong,Yiheng Yang,Zi-Jie Yan,Zihao Wang,Lingjie Zhou,Dingsong Wu,Houke Chen,Stephen Paolini,Bing Xia,Bomin Zhang,Xiaoda Liu,Hongtao Rong,Annie G. Wang,Saswata Mandal,Kaijie Yang,Benjamin N. Katz,Lunhui Hu,Jieyi Liu,Tien-Lin Lee,Vincent H. Crespi,Yuanxi Wang,Yulin Chen,… Cui-Zu Chang
Nature Materials  Published:13 April 2026
DOI:https://doi.org/10.1038/s41563-026-02573-y

Abstract

In low-dimensional superconductors, the interplay between quantum confinement and interfacial hybridization effects can reshape Cooper-pair wavefunctions and give rise to unconventional superconducting states. Here we use plasma-free confinement epitaxy assisted by a carbon buffer layer to synthesize a gallium trilayer sandwiched between graphene and a 6H-SiC(0001) substrate. Within this confined gallium layer, we demonstrate interfacial Ising-type superconductivity driven by atomic orbital hybridization. Electrical transport measurements reveal that the in-plane upper critical magnetic field reaches ~21.98 T at T = 400 mK, approximately 3.38 times the Pauli paramagnetic limit. Angle-resolved photoemission spectroscopy measurements, combined with theoretical calculations, confirm the presence of split Fermi surfaces with Ising-type spin textures at the K and K′ valleys of the confined gallium layer, originating from strong hybridization with the SiC substrate. This work establishes a strategy for realizing unconventional pairing wavefunctions through the synergistic combination of quantum confinement and interfacial hybridization effects.

1701物理及び化学
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