2026-08-31 北海道大学,科学技術振興機構,⼤阪公⽴⼤学,広島大学,高輝度光科学研究センター,東北大学,東京都立大学
Li₃PS₄多形体の合成経路を描いた時間-温度-変態（TTT）図
＜関連情報＞
- https://www.hokudai.ac.jp/news/2026/08/post-2431.html
- https://www.nature.com/articles/s41467-026-76661-7
準安定α-Li₃PS₄の核生成と急冷性を探るための時間-温度-変態図 Time-Temperature-Transformation Diagrams to Navigate the Nucleation and Quenchability of Metastable α-Li₃PS4
Akira Miura,Woohyeon Baek,Yuta Fujii,Kiyoharu Tadanaga,Rana Hossain,Aichi Yamashita,Yoshikazu Mizuguchi,Chikako Moriyoshi,Shintaro Kobayashi,Shogo Kawaguchi,Ding Jiong,Shigeo Mori,Atsushi Sakuda,Akitoshi Hayashi & Wenhao Sun
Nature Communications Published:22 August 2026
DOI:https://doi.org/10.1038/s41467-026-76661-7 Early provide
Abstract
α-Li₃PS₄ is a promising solid-state electrolyte with the highest ionic conductivity among its polymorphs. However, its formation presents a thermodynamic paradox: the α-phase is the equilibrium phase at high temperature and transforms to the stable γ-Li3PS4 polymorph when cooled to room temperature; however, α-Li3PS4 can be synthesized and quenched in a metastable state via rapid heating at relatively low temperatures. The origin of this synthesizability and anomalous stability has remained elusive. Here, we address this paradox by presenting an experimental and computational time-temperature-transformation (TTT) diagram, constructed from a temperature-size phase diagram and experimental high-time-resolution isothermal measurements. Our density functional theory calculations reveal that at the nanoscale, the α-phase is stabilized by its low surface energy, which drastically lowers its nucleation barrier across a wide temperature range. This size-dependent stabilization is directly visualized using in-situ sub-second synchrotron X-ray diffraction and electron microscopy, capturing the rapid nucleation of nano-sized α-Li3PS4 and its subsequent slow transformation. This work presents a generalizable framework that integrates thermodynamic and kinetic factors for understanding nucleation and phase transformation mechanisms, providing a rational strategy for the targeted synthesis of functional metastable materials.
