三層ニッケル酸化物におけるほぼ等方的超伝導特性を解明(Researchers Reveal Nearly Isotropic Superconducting Property in Trilayer Nickelate)

2026-04-17 合肥物質科学研究院(HFIPS)

中国科学院合肥物質科学研究院のZHANG Jinglei教授らは、三層ニッケル酸化物La4Ni3O10-δが高圧下でほぼ等方的な上部臨界磁場を示すことを発見した。層状超伝導体では通常強い異方性が現れるが、本研究では温度全域で方向依存性がほとんど見られなかった。研究チームは強磁場・高圧・極低温を同時に実現する新測定系を開発し、磁場方向ごとの特性を精密に評価。その結果、異なる電子状態(2バンド)が逆の異方性を持ち、相互に打ち消し合うことで等方的挙動が生じると示唆された。この成果はニッケル系超伝導の機構解明に重要な手がかりを与えるとともに、極限条件下での量子物質研究手法を拡張するものである。

三層ニッケル酸化物におけるほぼ等方的超伝導特性を解明(Researchers Reveal Nearly Isotropic Superconducting Property in Trilayer Nickelate)
Phase diagram of the superconducting upper critical field of trilayer nickelate La4Ni3O10-δ along two orientations under high magnetic field (Image by BIAN Yaolong)

<関連情報>

加圧下にある三層構造ニッケレートLa4⁢Ni3⁢O10−におけるほぼ等方性の上限臨界磁場 Nearly Isotropic Upper Critical Field in Pressurized Trilayer Nickelate La4⁢Ni3⁢O10−

Di Peng, Yaolong Bian, Zhenfang Xing, Lixing Chen, Jiaqiang Cai, Tao Luo, Fujun Lan, Yuxin Liu, Yinghao Zhu
Physical Review X  Published: 8 April, 2026
DOI: https://doi.org/10.1103/h5sv-dzd1

Abstract

Evidence of superconductivity has recently been reported in pressurized nickelates, providing a new platform to explore high-temperature superconductivity. However, detailed experimental characterization of the superconducting properties of nickelates under pressure remains limited and technically challenging. Here, we report the first full temperature-dependent measurements of the upper critical field (0⁢⁢2) in pressurized trilayer nickelate La4⁢Ni3⁢O10− single crystal, achieved by integrating advanced high-magnetic-field and high-pressure techniques. Remarkably, La4⁢Ni3⁢O10− exhibits nearly isotropic superconductivity, with the anisotropic parameter decreasing monotonically from 1.4 near to 1 at lower temperatures. By applying a two-band model analysis out of plane and in plane 0⁢⁢2, we uncover a compensation of anisotropic diffusivity between bands primarily originating from 2 and 22 orbitals, resulting in an exceptionally isotropic superconducting characteristic. These findings indicate the significant contribution of the 2 orbital to superconductivity in pressurized La4⁢Ni3⁢O10− and provide essential constraints for theoretical models of the pairing mechanism in Ruddlesden-Popper nickelates.

1701物理及び化学99未分類
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