2025-06-13 カリフォルニア大学ロサンゼルス校 (UCLA)
＜関連情報＞
- https://newsroom.ucla.edu/stories/next-generation-of-batteries-may-get-lifespan-boost-with-help-from-new-ucla-imaging-techniques
- https://www.science.org/doi/10.1126/sciadv.adv3191
電気化クライオ電子顕微鏡によるダイナミックな電池ナノ界面のトラッピングとイメージング Trapping and imaging dynamic battery nanointerfaces via electrified cryo-EM
Chongzhen Wang, Jung Tae Kim, Xintong Yuan, Jin Koo Kim, […] , and Yuzhang Li
Science Advances Published:13 Jun 2025
DOI:https://doi.org/10.1126/sciadv.adv3191
Abstract
The electrified interface between a liquid and a solid underpins diverse phenomena, from ion-transfer during battery operation to action potentials enabling biological communication. However, conventional tools are blind to the nanoscale dynamics of this metastable interface. Here, we leverage electrified cryo–electron microscopy (eCryo-EM), a technique that rapidly freezes and kinetically traps these dynamic, nonequilibrium states during battery operation for nanoscale characterization. Collective snapshots of the electrified interface at controlled time intervals quantifies early-stage growth kinetics of the solid electrolyte interphase (SEI), a passivation film that governs electron and ion transport. Unexpectedly, the diffusivity of charged species of the two SEI films with differing chemistry and performance are estimated to be within 10% of the other, indicated by the slope of their diffusion-limited SEI growth regimes. Instead, the slope of the reaction-limited SEI growth regimes differs by a factor of 3, suggesting that lowered reactivity of the high-performance electrolyte is largely responsible for its high coulombic efficiency.
