リチウムイオン電池の材料が急速充電の壁を破る(Lithium-ion battery material breaks barrier on fast charging)

2022-09-21 オークリッジ国立研究所(ORNL)

＜関連情報＞

• https://www.ornl.gov/news/lithium-ion-battery-material-breaks-barrier-fast-charging
• https://onlinelibrary.wiley.com/doi/10.1002/aenm.202200519

高性能リチウムイオン電池用新規負極材Mo1.5W1.5Nb14O44の高速充放電特性に関する知見 Insight into the Fast-Rechargeability of a Novel Mo1.5W1.5Nb14O44 Anode Material for High-Performance Lithium-Ion Batteries

Runming Tao,Tianyu Zhang,Susheng Tan,Charl J. Jafta,Cheng Li,Jiyuan Liang,Xiao-Guang Sun,Tao Wang,Juntian Fan,Ziyang Lu,Craig A. Bridges,Xian Suo,Chi-Linh Do-Thanh,Sheng Dai
Advanced Energy Materials  Published: 22 July 2022
DOI:https://doi.org/10.1002/aenm.202200519

Abstract

Wadsley–Roth phased niobates are promising anode materials for lithium-ion batteries, while their inherently low electrical conductivity still limits their rate-capability. Herein, a novel doped Mo_1.5W_1.5Nb₁₄O₄₄ (MWNO) material is facilely prepared via an ionothermal-synthesis-assisted doping strategy. The detailed crystal structure of MWNO is characterized by neutron powder diffraction and aberration corrected scanning transmission electron microscope, unveiling the full occupation of Mo⁶⁺-dopant at the t1 tetrahedral site. In half-cells, MWNO exhibits enhanced fast-rechargeability. The origin of the improved performance is investigated by ultraviolet–visible diffuse reflectance spectroscopy, density functional theory (DFT) computation, and electrochemical impedance spectroscopy, revealing that bandgap narrowing improves the electrical conductivity of MWNO. Furthermore, operando X-ray diffraction elucidates that MWNO exhibits a typical solid-solution phase conversion-based lithium-ion insertion/extraction mechanism with reversible structural evolution during the electrochemical reaction. The boosted lithium-ion diffusivity of MWNO, due to the Mo⁶⁺/W⁶⁺ doping effect, is confirmed by a galvanostatic intermittent titration technique and DFT. With the simultaneously enhanced electrical conductivity and lithium-ion diffusivity, MWNO successfully demonstrates its fast-rechargeability and practicality in the LiNi_0.5Mn_1.5O₄-coupled full-cells. Therefore, this work illustrates the potential of ionothermal synthesis in energy storage materials and provides a mechanistic understanding of the doping effect on improving material’s electrochemical performance.