殺生物剤を使わない船底防汚塗料が最も高性能であることを実証(Biocide-free antifouling paint performs best against fouling)

2026-06-16 チャルマース工科大学

スウェーデンのチャルマース工科大学を中心とする研究チームは、レジャーボート向け防汚塗料(antifouling paint)の性能と環境影響を比較評価し、生物殺傷剤(バイオサイド)を含まないシリコーン系塗料が最も優れた防汚性能を示すことを明らかにした。研究では、銅含有量の異なる5種類の銅系塗料、シリコーン系無毒塗料1種類、トラロピリルと亜鉛ピリチオンを含む塗料1種類の計7製品を対象に、スウェーデン、デンマーク、フランスの沿岸海域で最大6か月間の曝露試験を実施した。その結果、シリコーン系塗料が最も効果的に付着生物の成長を抑制し、銅系塗料は銅含有量が大きく異なっても防汚効果に有意差が見られなかった。また、「環境に優しい」と販売されているトラロピリル系塗料は極めて高い生態毒性を示し、環境リスク評価では許容基準を大幅に超える結果となった。研究は、高濃度銅塗料の使用削減や、低毒性で高性能なシリコーン系塗料への転換が海洋環境保全に有効であることを示している。

<関連情報>

レジャーボート用防汚塗料の持続可能性ランキング – 有効性と環境影響のバランス Sustainability ranking of antifouling coatings for leisure boats – Balancing efficacy and environmental impact

Maria Lagerström, Florane Le Bihanic, Laura Veensalu, Rémy Boisserie-Gimenez, Lola Racofier, Ann I. Larsson, Marcel Butschle, Gwendolina Limon, Xavier Cousin, Kai Bester, Jérôme Cachot
Journal of Hazardous Materials  Available online: 26 February 2026
DOI:https://doi.org/10.1016/j.jhazmat.2026.141600

殺生物剤を使わない船底防汚塗料が最も高性能であることを実証(Biocide-free antifouling paint performs best against fouling)

Highlights

  • Sustainability assessment of seven antifouling coatings for leisure boats.
  • Combined field efficacy, environmental risk modeling and ecotoxicity testing.
  • Biocide-free silicone coating ranked most sustainable with low toxicity.
  • Tralopyril-based coating exhibited high toxicity and environmental risk.
  • Copper coatings met environmental risk criteria only at one of three study sites.

Abstract

Antifouling coatings are widely used on leisure boats to prevent biofouling, yet their environmental impacts vary significantly depending on formulation. This study systematically evaluated seven commercial antifouling products, including five copper-based coatings (with varying cuprous oxide content), one tralopyril-based coating and one biocide-free silicone foul-release coating. The evaluation included three complementary approaches: field-based efficacy testing, environmental risk assessment (ERA) modeling and ecotoxicological assays. Field trials were conducted over six months at three European coastal sites (Skagerrak, Kattegat and Atlantic) to assess the antifouling performance. Biocide release rates were quantified using X-ray Fluorescence and used to model environmental risks in accordance with EU guidelines. Acute toxicity of leachates was tested on four marine species (Aliivibrio fischeri, Phaeodactylum tricornutum, Artemia salina larvae and Oryzias melastigma larvae). The biocide-free silicone coating ranked highest in sustainability, combining strong antifouling efficacy with minimal acute toxicity. The copper-based coatings typically showed comparable efficacy at all sites despite differences in copper release but some only passed ERA thresholds in one of the sites (Atlantic). Lower copper content formulations generally exhibited reduced environmental impact. The tralopyril-based coating, despite being marketed as “environmentally safe”, demonstrated the highest toxicity and environmental risk. These findings highlight the need for environmental assessment of antifouling products to validate environmental safety claims and to promote lower impact formulations. While ERA modeling is suitable for biocidal products, ecotoxicological testing remains essential for biocide-free alternatives. Improved and standardized leaching protocols are needed to better reflect real-world conditions and support sustainable product development.

1901環境保全計画
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