電子が描くナノスケールの“右巻き・左巻きの波紋”~カゴメ金属で見えた“カイラリティ”の起源~

2025-10-31 名古屋大学

名古屋大学と京都大学の研究チームは、カゴメ格子構造をもつ金属化合物で観測される「カイラル電子干渉」の起源を理論的に解明した。電子の波紋が右巻き・左巻きを示す現象は、鏡映対称性が破れた「ループ電流相」に由来することを発見。カゴメ金属AV₃Sb₅で不純物の影響を考慮した解析により、微小な磁場で反転するカイラリティの仕組みを説明した。この成果は非従来型超伝導の理解にも寄与し、量子物質研究の新展開を示す。成果は『Nature Communications』に掲載。

電子が描くナノスケールの“右巻き・左巻きの波紋”~カゴメ金属で見えた“カイラリティ”の起源~

<関連情報>

走査トンネル顕微鏡によるカゴメ金属のループカレント相におけるスイッチング可能な準粒子干渉カイラリティの起源 Origin of switchable quasiparticle-interference chirality in loop-current phase of kagome metals measured by scanning-tunneling-microscopy

Seigo Nakazawa,Rina Tazai,Youichi Yamakawa,Seiichiro Onari & Hiroshi Kontani
Nature Communications  Published:29 October 2025
DOI:https://doi.org/10.1038/s41467-025-64588-4

Abstract

In the kagome superconductors AV3Sb5 (A=Cs,Rb,K), a cascade of correlated electron phases cause exotic symmetry-breaking quantum states. In particular, the dissipationless chiral loop-current phase has been attracting increasing attention. A crucial clue is offered by the chirality of the quasiparticle interference signal observed in scanning tunneling microscopy. However, the connection between loop-current chirality and quasiparticle interference chirality remains poorly understood. Here, we reveal theoretically that a pronounced chiral quasiparticle interference signal emerges in the extremely dilute impurity regime ( ≲ 0.1%). A single impurity at site Z induces a quasiparticle interference chirality χZ = ± 1, determined by the direction of the Z3 nematicity, itself set by the relative position of the loop-current order in the star-of-David charge-density-wave phase. Notably, even a small magnetic field can smoothly switch the chirality, leading to field-induced shear lattice strain consistent with recent experiments. Our theoretical study provide key insights into the nature of the loop-current-induced symmetry-breaking states in kagome metals.

1700応用理学一般
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