ミュー粒子を使って超伝導電子ペアの状態を解明~隣接する超伝導体の作る落とし穴に警鐘~

2026-02-12 京都大学

京都大学・高等研究院豊田理研-京大連携拠点(TRiKUC)などの研究グループは、ミュー粒子を用いた磁気共鳴(ミューオン・ナイトシフト)測定により、ルテニウム酸化物Sr₂RuO₄の超伝導電子対が従来有力視されてきたスピン三重項ではなく、スピン一重項で整合的に説明できることを示し、『Physical Review Letters』に発表した。さらに、複数試料を並べた従来手法では、隣接する超伝導体のマイスナー効果による漏れ磁場が信号に影響するという実験上の落とし穴を解明。非従来型超伝導の理解に重要な知見を与える成果である。

ミュー粒子を使って超伝導電子ペアの状態を解明~隣接する超伝導体の作る落とし穴に警鐘~

<関連情報>

Sr₂RuO₄の超伝導対称性を精密に探るミューオンナイトシフト Muon Knight Shift as a Precise Probe of the Superconducting Symmetry of Sr2⁢RuO4Hisakazu

Matsuki, Rustem Khasanov, Jonas A. Krieger, Thomas J. Hicken, Kosuke Yuchi, Jake S. Bobowski, Giordano Mattoni, Atsutoshi Ikeda, Ryutaro Okuma et al.
Physical Review Letters  Published: 9 February, 2026
DOI: https://doi.org/10.1103/sgcz-9rc7

Abstract

Muon spin rotation (⁢μSR) measurements of internal magnetic field shifts, known as the muon Knight shift, are used for determining pairing symmetries in superconductors. While this technique has been especially effective for -electron-based heavy-fermion superconductors, it remains challenging in -electron-based superconductors such as Sr2⁢RuO4, where the Knight shift is intrinsically small. Here, we report high-precision muon Knight shift measurements of superconducting Sr2⁢RuO4. We observe that using multiple pieces of crystals, a common practice in ⁢⁢μSR measurements, induces a substantial paramagnetic shift below the superconducting transition temperature, Tc, when a weak magnetic field is applied. We attribute such an unresolved paramagnetic shift to stray fields generated by neighboring diamagnetic crystals. To avoid this, one piece of crystal was used in this Letter. We experimentally determine the muon Knight shift of Sr2⁢RuO4 in the normal state to be −116±7  ppm. By combining the observed muon Knight shift with independently determined bulk magnetization data from the same crystal used in ⁢μ⁢SR and carefully separating various contributions to the shift, we confirm a significant reduction in the spin Knight shift below Tc, consistent with spin-singlet-like pairing. This result constitutes the precise muon Knight shift measurement in a -electron-based superconductor. Our results highlight the potential of ⁢⁢μSR as a powerful complementary technique to the established method of nuclear magnetic resonance for probing the spin susceptibility in superconductors.

1700応用理学一般
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