湿潤環境でも形状を維持する高機能絹を開発 ―セルロースナノファイバー添加飼料により高強度・高寸法安定性を実現―

2026-07-14 東北大学

東北大学の研究グループは、カイコの飼料に植物由来のセルロースナノファイバー(CNF)を添加することで、高強度かつ湿潤環境でも形状を維持できる高機能な絹の開発に成功した。CNF添加飼料で育てたカイコから得られた絹について、単糸、撚糸、織物の各段階で評価した結果、引張強度は単糸で約50%向上し、その効果は撚糸や織物でも維持された。さらに、水を吸収した後の乾燥時に生じる収縮が大幅に抑制され、撚糸では従来品の4分の1以下まで縮みが低減し、高い寸法安定性を示した。これはCNFが絹の内部構造を補強し、水分による変形を抑制したためと考えられる。本成果は、化学的な後加工を施さず、天然由来材料のみで絹の性能を向上させる新たな材料設計手法を示すものであり、高機能繊維、医療・バイオ材料、産業資材、サステナブル素材など幅広い分野への応用が期待される。

湿潤環境でも形状を維持する高機能絹を開発 ―セルロースナノファイバー添加飼料により高強度・高寸法安定性を実現―
図1.CNF添加飼料による絹織物の強度増加

<関連情報>

蚕の給餌によるセルロースナノファイバー強化絹織物の引張特性と寸法安定性 Tensile properties and dimensional stability of cellulose nanofiber-reinforced silk fabrics by silkworm feeding

Camille Moreau, Hiroki Kurita, […], and Fumio Narita
Journal of Industrial Textiles  Published:June 25, 2026
DOI:https://doi.org/10.1177/15280837261463657

Abstract

Cellulose nanofiber (CNF) reinforcement of silk fibroin (SF) has attracted increasing attention as a sustainable strategy for enhancing the mechanical performance of silk materials. In this study, CNF-reinforced silk was produced by directly feeding silkworms (Bombyx mori) with artificial diets containing CNF, and its mechanical properties and dimensional stability were systematically investigated across three hierarchical levels: single filaments, twisted yarns, and woven fabrics. At the single-filament level, the addition of 5 wt.% CNF resulted in significant increases in Young’s modulus and ultimate tensile strength, while the fracture elongation remained nearly unchanged. These improvements were retained at the yarn and fabric levels. The dimensional changes induced by water-absorption, swelling and subsequent drying were thereby quantitatively evaluated. While individual filaments exhibited negligible shrinkage regardless of CNF addition, twisted yarns and fabrics showed pronounced shrinkage, which was markedly suppressed by CNF reinforcement. Notably, the shrinkage rate of CNF-reinforced twisted yarns was reduced to less than one-quarter of that of unreinforced yarns. FT-IR analysis based on the amide III region revealed that CNF addition did not significantly increase the β-sheet crystallinity of single filaments, indicating that the enhanced dimensional stability does not originate from increased crystalline content. Instead, CNF is suggested to stabilize higher-order assemblies by restricting molecular mobility in amorphous regions and reinforcing inter-fiber interactions. These findings provide new insight into the multiscale design of silk-based materials with improved mechanical performance and moisture resistance.

0604繊維二次製品の製造及び評価
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