超高速化を実現した強誘電体紫外線フォトディテクタの開発 (Novel Ferroelectric Ultraviolet Photodetector Achieves Near-Ten-Thousand-Fold Speed Increase)

2025-01-19 中国科学院(CAS)

中国科学院金属研究所(IMR)の研究チームは、従来の強誘電体光検出器が抱えてきた応答速度の限界を克服する新しい紫外線フォトディテクター材料を開発し、Nature Communications に発表した。開発された磁鉛鉱型化合物 SrAl₁₁₋δTiO₁₉(SATO)の高品質薄膜は、c軸方向に分極した単一ドメイン構造を持ち、キャリアを阻害するドメイン壁散乱を本質的に排除する。これにより、波長330 nmで高感度(応答度860 mA/W、検出能1.63×10¹³ Jones)と低ノイズを両立し、立ち上がり/立ち下がり速度6.8 ns/17.7 nsという従来比で約1万倍高速な応答を実現した。本成果は、超高速・高精度な次世代光検出技術への道を開く。

超高速化を実現した強誘電体紫外線フォトディテクタの開発 (Novel Ferroelectric Ultraviolet Photodetector Achieves Near-Ten-Thousand-Fold Speed Increase)
Microstructure of AlN and SATO thin films. (a, b) Bright-field transmission electron microscopy (TEM) image and selected area electron diffraction (SAED) pattern of the AlN/STO cross-sectional sample. (c, d) Bright-field TEM image and SAED pattern of the SATO/STO cross-sectional sample. No obvious ferroelectric domain walls were observed in the SATO thin film, indicating its single-domain characteristic. Scale bars: 20 nm. (Image by IMR)

<関連情報>

超高速応答速度を有する強誘電体紫外線光検出器材料 Ferroelectric ultraviolet photodetector material with ultrafast response speed

Xuexi Yan,Tingting Yan,Lingli Li,Yi Cao,Xinwei Wang,Jinghui Wang,Ang Tao,Tingting Yao,Yixiao Jiang,Weijin Hu,Xiaosheng Fang,Hengqiang Ye,Xiu-Liang Ma & Chunlin Chen
Nature Communications  Published:30 December 2025
DOI:https://doi.org/10.1038/s41467-025-68069-6

We are providing an unedited version of this manuscript to give early access to its findings. Before final publication, the manuscript will undergo further editing. Please note there may be errors present which affect the content, and all legal disclaimers apply.

Abstract

Ferroelectric films are promising to be used for high-performance photodetectors due to their intrinsic electric fields and high dielectric constants. However, the presence of high-density domains with varying polarization directions can severely degrade comprehensive performance. Here, we fabricate high-quality SrAl11-δTiO19 (SATO) ferroelectric films through a solid-state reaction. The SATO film possesses a magnetoplumbite-type structure with polarization along the c-axis and exhibits the possibility of single-domain ferroelectrics. Ferroelectric performance tests show that the remnant polarization of SATO film reaches 7.8 μC/cm2 and the polarization retention exceeds 500 hours. Optoelectronic performance measurements reveal that the SATO photodetector exhibits excellent performance with response wavelength of 330 nm, responsivity of 860 mA/W, detectivity of 1.63 × 1013 Jones, switching ratio of 1.9 × 104, and ultrafast rise/fall response speed of 6.8 ns/17.7 ns (i.e., nearly 10000 times faster than traditional photodetectors). The outstanding properties highlight SATO as an outstanding candidate for next-generation photodetectors.

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