超伝導の常識を覆す発見―スピン三重項超伝導体だけがもつ特別な性質―

2024-03-24 京都大学

本研究は、京都大学を中心とした共同研究により、スピン三重項超伝導体UTe₂に特有の新しい性質を発見した。超伝導は通常、スピン一重項状態で成立し、スピン磁化率が常伝導と同等になると破壊されるが、本研究では三重項超伝導においては逆に超伝導が強化されることを確認した。24テスラの高磁場下で精密測定を行い、スピン磁化率が常伝導と同じになる条件で超伝導がより強固になることを実証。この特異な振る舞いは三重項超伝導体特有であり、UTe₂がその代表例であることを裏付けた。従来の超伝導理論の常識を覆す成果であり、新奇量子現象の理解や次世代量子材料開発への貢献が期待される。

超伝導の常識を覆す発見―スピン三重項超伝導体だけがもつ特別な性質―
磁場をc軸に印可した時の超伝導臨界磁場Hc2(黄丸)の温度依存性。

<関連情報>

UTe2における三重項超伝導対のスピン配置と超伝導との密接な相関 Intimate relationship between spin configuration in the triplet pair and superconductivity in UTe2

Hiroki Matsumura, Yuki Takahashi, Riku Matsubayashi, Katsuki Kinjo, Shunsaku Kitagawa, Kenji Ishida, Yo Tokunaga, Hironori Sakai, Shinsaku Kambe et al.
Physical Review B  Published: 10 March, 2026
DOI: https://doi.org/10.1103/xr3p-cxbt

Abstract

Spin-triplet superconductivity is an intriguing quantum coherent state with both spin and orbital degrees of freedom, which holds significant potential for future applications in quantum technology. However, how the spin of the triplet pairs responds to an external magnetic field remains poorly understood. This is mainly due to the absence of suitable spin-triplet superconductors. Here, we report results of Knight-shift and ac-susceptibility measurements on UTe2. We demonstrate that the spin susceptibility, which slightly decreases compared to the normal-state value below the superconducting (SC) transition temperature c, is rapidly restored and nearly recovers to the normal-state values around 5 T, well below the SC upper critical field ⁢2 when the magnetic field is applied along the axis (H∥c). In addition, we found that c⁢2 of superconductivity becomes larger when the SC spin aligns with the magnetic field. By considering the results on H∥b, our results suggest the presence of a close relationship between the spin configuration of the triplet pair and c⁢2, as well as the anisotropic pinning interaction acting on the triplet pairs. These phenomena, which have never been observed in spin-singlet superconductors, represent characteristic features unique to spin-triplet superconductors. We discuss the similarities between superconductivity in UTe2 and superfluid 3He, focusing on their spin-triplet pairing states.

1701物理及び化学
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