3つの非線形光学材料を合成、200nm以下のカットオフを実現（Scientists Synthesize Three Nonlinear Optical Materials with Sub-200 nm Cutoff Edges）

2025-11-03 中国科学院（CAS）

＜関連情報＞

• https://english.cas.cn/newsroom/research_news/chem/202511/t20251104_1095606.shtml
• https://advanced.onlinelibrary.wiley.com/doi/10.1002/adfm.202520516

[B3O6 ]を介した構造制御による希土類金属ホウ酸塩フッ化物における先進的なUV NLO結晶の実現 Unlocking Advanced UV NLO Crystals in Rare-Earth Metal Borate Fluorides via [B3O6]-Mediated Structural Modulation

Qianzhen Zhang, Ran An, Abudukadi Tudi, Jiongquan Chen, Xiaoqin Ma, Xifa Long, Zhihua Yang, Shilie Pan, Yun Yang
Advanced Functional Materials  Published: 17 October 2025
DOI:https://doi.org/10.1002/adfm.202520516

Abstract

Developing new short-wavelength nonlinear optical (NLO) crystals has always been a significant and challenging area of research. Herein, guided by the cooperative optimization strategy, three new rare-earth metal borate fluorides, K₂GdB₃O₆F₂, Rb₂LuB₃O₆F₂, and Cs₂LuB₃O₆F₂, are rationally designed and fabricated by synergically assembling advantageous functional groups. Among them, a structural evolution from centrosymmetric K₂GdB₃O₆F₂ to non-centrosymmetric Rb₂LuB₃O₆F₂ and Cs₂LuB₃O₆F₂ reveals that the [B₃O₆] group contributes to the control of structural symmetry, owing to its sensitivity to the coordination of rare earth metal polyhedra. Notably, all the three title compounds exhibit short cutoff edges less than 200 nm, with Cs₂LuB₃O₆F₂ displaying a large experimental frequency doubling effect of 1.5 × KH₂PO₄. The type-I shortest phase-matching wavelengths for Rb₂LuB₃O₆F₂ and Cs₂LuB₃O₆F₂ are evaluated to be 210 and 202 nm, respectively, indicating their potential for direct output of 213 coherent lights through a fifth harmonic generation process of Nd: YAG laser. This study provides new insights into the rational design and development of short-wavelength NLO materials by exploring the sensitivity of the [B₃O₆] groups to the surrounding coordination environment, thereby fostering innovation in the field of NLO materials.