電池の熱暴走を超高効率・低コストで検出~安全な蓄電池開発を加速~

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2025-04-04 東京大学

東京大学と物質・材料研究機構(NIMS)の研究チームは、リチウムイオン電池の「熱暴走」を短時間・低コストで検出可能な新手法を開発しました。従来の50分の1サイズの小型電池を用いることで、少量の材料で熱暴走挙動を定量的に評価可能にし、材料や設計、劣化条件の影響を効率的にスクリーニングできます。これにより、安全性を高度に担保した蓄電池の開発が加速され、カーボンニュートラル社会の実現にも寄与します。研究成果は2025年に『Nature Energy』誌に掲載されました

<関連情報>

実験室規模の小型電池を用いた加速熱量測定による迅速な安全性スクリーニングの実現 Rapid safety screening realized by accelerating rate calorimetry with lab-scale small batteries

Seongjae Ko,Hiromi Otsuka,Shin Kimura,Yuta Takagi,Shoji Yamaguchi,Takuya Masuda & Atsuo Yamada
Nature Energy  Published:02 April 2025
DOI:https://doi.org/10.1038/s41560-025-01751-7

電池の熱暴走を超高効率・低コストで検出~安全な蓄電池開発を加速~

Abstract

The increasing energy density and size requirements have necessitated the establishment of reliable safety technologies for rechargeable batteries. In particular, understanding and controlling thermal runaway, an uncontrollable heat generation from continuous exothermic reactions in batteries, is essential for developing high-safety batteries. However, comprehensive safety evaluations at the full-cell level are limited by size requirements (greater than the ampere-hour scale) for performing accelerating rate calorimetry tests that can provide critical information on heat generation during thermal runaway. Further, efficient safety screening is difficult because of substantial quantities of battery materials and costly manufacturing processes. Here we designed cylindrical pouch-type small batteries (~21 mAh, ~0.1 g of cathode active materials) that are highly susceptible to heat generation, thus allowing us to perform full-cell-level accelerating rate calorimetry tests on a laboratory scale. This enables rapid safety screening and early-stage feedback for battery design, which can help accelerate the development of high-safety batteries.

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