バイオソリッドから重金属を回収する技術革新で “金字塔”(Engineers “strike gold” with innovation that recovers heavy metals from biosolids)

2023-06-22 ロイヤルメルボルン工科大学(RMIT)

The high-value biochar produced through the patented RMIT technology. Credit: Shawn Smits Photography

＜関連情報＞

• https://www.rmit.edu.au/news/all-news/2023/jun/heavy-metals-removal
• https://www.sciencedirect.com/science/article/abs/pii/S0304386X23000269

バイオソリッドから重金属を除去・回収するクローズドループの湿式冶金プロセスについて、弱酸性前処理を経由して調査した。 Investigations into the closed-loop hydrometallurgical process for heavy metals removal and recovery from biosolids via mild acid pre-treatment

Ibrahim Gbolahan Hakeem, Pobitra Halder, Shefali Aktar, Mojtaba Hedayati Marzbali, Abhishek Sharma, Aravind Surapaneni, Graeme Short, Jorge Paz-Ferreiro, Kalpit Shah
Hydrometallurgy  Available online: 2 March 2023
DOI:https://doi.org/10.1016/j.hydromet.2023.106044

Abstract

Biosolids contain heavy metals (HMs), restricting their beneficial reuse in agricultural land. However, these metals can be a valuable resource in many applications if recovered efficiently. Therefore, the removal and recovery of HMs and other limiting contaminants in biosolids without degrading the organic nutrients of the resulting treated biosolids demands holistic investigations. A closed-loop hydrometallurgical treatment process for metal removal and recovery from biosolids was developed in this study. Firstly, mild acid treatment using 3% v/v H₂SO₄ at 25 °C, 600 rpm for 30 min was performed in a 1 L continuous stirred tank reactor to extract common HMs (such as As, Cd, Co, Cr, Cu, Ni, Pb, and Zn) from biosolids into the aqueous phase. The effects of solids concentration and acid types on the HMs extraction efficiency were studied. Then, the primary acid leachate stream was continuously recycled for metal extraction from biosolids until the dissolved metals in the solution reached saturation concentration. After that, the dissolved metals were recovered in staged NaOH precipitation and adsorption. Low solids contents (<5% w/v) using mineral acids having pH <2 and oxidation-reduction potential (ORP) ∼500 mV (versus SHE) favoured HMs solubilisation from biosolids with an average extraction efficiency of 70%. The dissolution of ferric iron (Fe³⁺) by H₂SO₄ and subsequent in-situ formation of ferric sulfate enhanced the metal extraction strength of the spent leachate stream during recycling. However, the solids loading in each leaching process must be kept low to prevent ferric concentration build-up and precipitation as the leachate pH steadily increases above 2 during recycling. Amongst the metal recovery methods investigated, H₂O₂ oxidation prior to 2-stage NaOH precipitation had the highest efficiency with 75–95% HMs recovery. The clarified stream was used to neutralise the acidic treated biosolids to close the process loop. The complete process flowsheet was developed with mass balances, and the fate of nutrients (mainly C, N, and P) and major per– and polyfluoro alkyl substances (PFAS) were overviewed.