強誘電体薄膜における3次元「極性カイラル・ボバー」の発見(3D “Polar Chiral Bobbers” Identified in Ferroelectric Thin Films)

2026-02-03 中国科学院(CAS)

中国科学院の金属研究所(IMR)と松山湖材料実験室などの共同研究チームは、強誘電体酸化物薄膜中に新しい三次元(3D)分極トポロジー構造「ポーラーカイラル・ボバー」を発見した。PbTiO₃超薄膜を対象に、位相場シミュレーションと球面収差補正透過電子顕微鏡を組み合わせて理論予測と実証を行った。この構造は、表面から内部のブロッホ点で終端する逆向き分極コアと、その周囲の渦状面内分極から成り、カイラリティを持つ点が特徴である。回転方向、分極の上下、位置の組み合わせにより最大8状態を安定に保持でき、従来の2値記録を超える高密度多値不揮発メモリへの応用が期待される。

強誘電体薄膜における3次元「極性カイラル・ボバー」の発見(3D “Polar Chiral Bobbers” Identified in Ferroelectric Thin Films)
Phase-field simulation predicts the emergence of polar chiral bobbers in (111)-oriented ultrathin PbTiO₃ ferroelectric films and reveals their polarization characteristics. (Image by IMR)

<関連情報>

酸化物強誘電体における多状態極性カイラルボバー Multistate Polar Chiral Bobbers in Oxide Ferroelectrics

Xiang-Wei Guo, Min-Jie Zou, Yun-Long Tang, Yin-Lian Zhu, Yu-Jia Wang, Xiu-Liang Ma
Advanced Materials  Published: 30 January 2026
DOI:https://doi.org/10.1002/adma.202510518

ABSTRACT

Polar topologies in ferroelectric oxides have potential applications in future electronic devices, such as high-density non-volatile memory and logic devices. However, their application in multistate storage remains largely unexplored, because the number of accessible topological states is limited. Here, we report a family of polar chiral bobbers in ultrathin (111)-oriented ferroelectric PbTiO3 films by combining phase-field simulations with aberration-corrected transmission electron microscopy. We find that a chiral bobber can exhibit eight distinct states, which can be applied to multistate storage exceeding the traditional binary (0/1) encoding. The polar chiral bobber can be easily manipulated with low energy to enable transitions between different states. These results suggest that polar chiral bobbers represent one of the promising candidates for applications in next-generation topological electronics, advanced memory, and quantum computing.

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