星間分子雲中の多環芳香族炭化水素の重要な役割を解明(Researchers Reveal Key Role of Interstellar Polycyclic Aromatic Hydrocarbons in Molecular Clouds)

2025-11-21 中国科学院(CAS)

中国科学院・新疆天文台の葛繼興研究員らは、星形成のゆりかごである分子雲における多環芳香族炭化水素(PAHs)の化学的役割を解明した。研究チームは39の分子雲サンプルを収集し、分子種の観測データをもとにPAHsを組み込んだ宇宙化学モデルを構築。分子雲の進化段階ごとに分子存在量を比較したところ、PAHsをモデルに含めることで、大多数のサンプルで観測との整合性が向上した。また、PAHsの導入は最適化された「化学年齢」に大きな影響を与えず、この化学年齢を分子雲の運動学的年齢推定に用いる妥当性も示された。さらに、PAHsの存在を示す指標分子のリストを提示し、将来の観測・生命前駆分子の起源研究に重要な基盤を提供している。

星間分子雲中の多環芳香族炭化水素の重要な役割を解明(Researchers Reveal Key Role of Interstellar Polycyclic Aromatic Hydrocarbons in Molecular Clouds)
The agreements between model and the sample。Black–without PAHs;cyan- with PAHs. The upper and lower panels are for the models with low (L) and high (H) metal initial abundances to the models respectively. (Image by XAO)

<関連情報>

冷たく高密度の雲核の異なる進化段階における天体化学モデリングにおける多環芳香族炭化水素の役割 The role of polycyclic aromatic hydrocarbons in astrochemical modeling at different evolutionary stages of cold dense cloud cores

Jixing Ge, Diego Mardones, Tie Liu, Natalia Inostroza-Pino, Yaping Peng and Jinhua He
Astronomy & Astrophysics  Published:16 October 2025
DOI:https://doi.org/10.1051/0004-6361/202452590

Abstract

Context. Although the role of PAHs have been highlighted in recent years, it is crucial to verify their functions at different evolutionary stages of dark cloud cores.

Aims. Fitting molecular abundances with gas-grain chemical models has revealed shorter chemical ages for denser cold dark cloud cores. To deepen the understanding of chemical ages and the functions of PAHs, we investigated the influence of PAHs in our chemical models by fitting observational data.

Methods. We collected observed molecular abundances (at least five species per core) from the literature for 39 cold dense cloud cores (T < 25 K and 104nH ≤ 107 cm−3). Using a gas-grain chemical model, we fit the molecular abundances of the 39 samples to determine the best-fit chemical ages and discuss the role of PAHs in an evolutionary view.

Results. We find an anticorrelation between the gas density and the fit chemical age through molecular abundance fitting. The best-fit chemical ages of the low-density cores (<7 × 104 cm−3) are comparable to the dynamical ages, which can be a good alternative indicator of physical age. However, for high-density cores (>7 × 104 cm−3), the chemical age is far from the physical age and therefore useless. The inclusion of PAHs do not change the estimation of the chemical ages much, which indicates the small effect of PAHs on average. However, we identified molecular tracers that are sensitive to PAHs at different evolutionary stages, thus revealing their diagnostic potential for chemical evolution.

1701物理及び化学
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