2025-05-02 ノースウェスタン大学
＜関連情報＞
- https://news.northwestern.edu/stories/2025/05/robotic-touch-sensors-contact/
- https://advanced.onlinelibrary.wiley.com/doi/10.1002/aelm.202400848
センサーの裏をかく： 導電性複合エラストマーの電気接触特性評価の重要性 Getting Under the Sensor’s Skin: The Importance of Electrical Contact Characterization for Conductive Composite Elastomers
Claire C. Onsager, Lev Rovinsky, Can C. Aygen, Shira K. Cohen, Noa Lachman, Matthew A. Grayson
Advanced Electronic Materials Published: 09 February 2025
DOI:https://doi.org/10.1002/aelm.202400848
Figure 3 SEM images of insulating surface interface (red frames) versus conducting bulk (green frames) for a) 3.5, b) 4.5, and c) 6 wt.% MWCNT. Enlarged images (bottom row) reveal MWCNT-poor surface layers of microscopic thickness dm around 200–400 nm, seemingly independent of MWCNT percentage. However, visible presence of nanotubes does not necessarily imply presence of conduction, if MWCNT concentration lies below the percolation threshold.
Abstract
Conductive elastomer composites can be used as flexible, lightweight, and inexpensive sensors, but they require ohmic electrical contacts to ensure readout consistency, and such contacts can suffer from hysteresis, non-ohmic behavior, and cyclic fatigue. This work investigates a common cause of non-ohmic conduction in such composite contacts, namely the thin insulating layer native to the surface of most silicone rubber composites that have been infused with multi-walled carbon nanotubes for piezoresistive sensing. Voltage sweep dc measurements of individual contacts on this surface layer behave as parallel head-to-tail diodes with asymmetric hysteresis. Frequency sweep ac measurements quantify the insulator thickness with a leaky capacitor model to be ∼1 µm, independent of nanotube concentration, much thicker than the apparent layer thickness as imaged with scanning electron microscopy. This analysis also confirms highly anisotropic bulk conduction, circa 100 times higher in-plane than cross-plane. To remove the surface layer, a simple surface abrasion is shown to achieve deep ohmic electrical contact to the elastomer bulk. A three-terminal method for verifying ohmic contacts is demonstrated and works even when all contacts are non-ohmic. This three-terminal method be easily applied to other conductive polymers for contact quality-testing.
