曲げ誘起層間すべりにより2次元材料の特性を変化させることに成功(Scientists Modulate 2D Material Properties via Bending-induced Interlayer Sliding)

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2025-04-07 中国科学院(CAS)

曲げ誘起層間すべりにより2次元材料の特性を変化させることに成功(Scientists Modulate 2D Material Properties via Bending-induced Interlayer Sliding)Atomic configurations and polarization textures in bent bilayer h-BN (Image by NIMTE)

中国科学院寧波材料技術与工程研究所(NIMTE)の研究チームは、機械的な曲げを利用して2次元層状材料の積層順序と物性を精密に制御する新手法を提案しました。層間滑りを誘発することで、電気分極の反転や電子・光学・磁気特性の変調を可能にし、次世代フレキシブルエレクトロニクスに応用可能な「滑りフレクソ応答」(例:フレクソ磁性、フレクソ光起電性など)を探る道を拓きました。h-BNやMoS₂などを用いた大規模原子シミュレーションにより、積層順序が電荷移動やドメイン壁形成に与える影響を解明。成果は『Physical Review Letters』誌に掲載されました。

<関連情報>

機械的曲げによる2次元スライディング強誘電体のスイッチング Switching Two-Dimensional Sliding Ferroelectrics by Mechanical Bending

Ri He, Hua Wang, Fenglin Deng, Yuxiang Gao, Bingwen Zhang, Yubai Shi, Run-Wei Li, and Zhicheng Zhong
Physical Review Letters  Published: 19 February, 2025
DOI: https://doi.org/10.1103/PhysRevLett.134.076101

Abstract

Two-dimensional van der Waals materials, possessing a unique stacking degree of freedom, offer an alternative strategy for modulating their properties through interlayer sliding. Controlling the stacking order is crucial for tuning material properties and developing slidetronics-based devices. Here, using machine-learning potentials, we propose a mechanical bending approach to manipulate stacking orders and related properties in sliding ferroelectric h-BN, 3R-MoS2, and nonferroelectric bilayer graphene. Our simulations predict the formation of irreversible kinks in bent bilayers, deviating from the expected arclike deformation. This kink formation arises from the interplay between bending energy and interlayer stacking energy. Notably, the bending-induced kink contains a ferroelectric topological domain wall that reverses the polarization of sliding ferroelectrics, a mechanism distinct from the conventional flexoelectric effect. This work proposes an exciting mechanical bending approach to dynamically manipulate the stacking order and associated optical, topological, ferroelectric, and magnetic properties in van der Waals layered materials.

1700応用理学一般
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