オルドビス紀の有機炭素同位体記録における初の完全なMDICEシグナルを解明(Researchers Reveal First Complete MDICE Signal in Ordovician Organic Carbon Isotope Record)

2025-09-10 中国科学院(CAS)

南京地質古生物研究所の呉栄昌教授ら国際共同研究チームは、中国南部・江南斜面のHule-1コアから得られたオルドビス紀中期の有機炭素同位体(δ¹³Corg)記録を解析し、世界で初めて「MDICE(中ダリウィル期炭素同位体正異常)」の完全なシグナルを確認した。従来は炭酸塩由来のδ¹³Ccarbに基づく研究が中心で、有機物記録は断片的だったが、本研究は約1.1‰の明瞭な正異常を三段階(上昇期・ピーク期・下降期)として同定。これにより、南中国でも堆積の空白なく深海堆積物に完全なMDICEが保存されていることが示された。国際比較によりMDICEの全球的同時性が確認され、当時の炭素循環の大規模な変動が寒冷化、海洋酸素化、生物多様化と密接に関連していた可能性が浮き彫りとなった。本成果はオルドビス紀層序対比の有効な指標を提供し、古環境と生物進化の共進化理解を進展させる。

オルドビス紀の有機炭素同位体記録における初の完全なMDICEシグナルを解明(Researchers Reveal First Complete MDICE Signal in Ordovician Organic Carbon Isotope Record)
Paleogeographic location of the Hule-1 core in the Jiangnan region, South China. (Image by NIGPAS)

<関連情報>

中国南方江南斜面におけるオルドビス紀(フロイアン-サンドビアン期)の高解像度炭素同位体層序:δ13CorgにおけるMDICEの初の完全記録とその地球規模的意義 High resolution Ordovician (Floian-Sandbian) carbon isotope stratigraphy from the Jiangnan slope, South China: The first complete record of the MDICE in δ13Corg and its global significance

Xiaocong Luan, Mikael Calner, Fangyi Gong, Oliver Lehnert, Guanzhou Yan, Yuchen Zhang, Zhutong Zhang, Rongchang Wu
Palaeogeography, Palaeoclimatology, Palaeoecology  Available online: 25 August 2025
DOI:https://doi.org/10.1016/j.palaeo.2025.113227

Highlights

  • Detailed litho-, bio- and chemostratigraphy on the Middle–Late Ordovician in Jiangnan slope, South China;
  • The most complete MDICE in δ13Corg data recorded worldwide so far;
  • Inferring more pronounced perturbation of the global carbon cycle during the Darriwilian Age.

Abstract

The Middle Darriwilian Isotopic Carbon Excursion (MDICE) is one of the globally recognized positive excursions in carbon isotope chemostratigraphy, but mainly documented by δ13Ccarb data in previous research. In this paper, new stable organic carbon isotope data (δ13Corg) are presented from the Hule-1 core from the southern Anhui Province of southern China. The core constitutes an Ordovician siliciclastic succession deposited in the upper Jiangnan slope. The Ordovician graptolite biostratigraphy of this area is already well established, and ranges from the Baltograptus deflexus Zone (Floian) to the Nemagraptus gracilis Zone (Sandbian). Based on the well-constructed graptolite biostratigraphy, a low-amplitude positive excursion of middle–late Darriwilian age within the Hulo Formation is confidently identified as the MDICE. The excursion has an amplitude of ca. 1.1‰ starting from the value of −28.0‰ near the base of this formation, reaching a peak at −26.9‰ in the middle, and decreasing to −28.5‰ in its upper part. Therefore, it reveals to our knowledge the globally best preserved and most complete δ13Corg record of MDICE hitherto. Our data elucidate the stratigraphic significance of the MDICE also in deeper depositional environments and as a tool for correlation across different lithofacies belts. The inferred perturbation of the global carbon cycle during this time interval was presumably more pronounced than previously thought, confirming that the Darriwilian was a critical time slice in terms of environmental and biosphere changes.

1702地球物理及び地球化学
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