2025-08-19 ノースウェスタン大学
＜関連情報＞
- https://news.northwestern.edu/stories/2025/08/clean-hydrogens-iridium-problem-solved-in-an-afternoon/
- https://pubs.acs.org/doi/10.1021/jacs.5c08326
メガライブラリを活用した酸素進化反応触媒の発見加速 Accelerating the Pace of Oxygen Evolution Reaction Catalyst Discovery through Megalibraries
Jin Huang,Zhe Wang,Jiashun Liang,Xiao-Yan Li,Jacob Pietryga,Zihao Ye,Peter T. Smith,Alp Kulaksizoglu,Connor R. McCormick,Jaerim Kim,Bosi Peng,Zeyan Liu,Ke Xie,Steven B. Torrisi,Joseph H. Montoya,Gang Wu,Edward H. Sargent,and Chad A. Mirkin
Journal of the American Chemical Society Published: August 19, 2025
DOI:https://doi.org/10.1021/jacs.5c08326
Abstract
Iridium (Ir) catalysts are essential for the acidic oxygen evolution reaction (OER) in proton-exchange membrane water electrolyzers (PEMWEs), but their high cost, scarcity, and geographical concentration limit large-scale adoption. In addition, the discovery of non-Ir alternatives is slow due to the vast design space possible. Here, a “megalibrary” is used to explore the catalytic activity of ∼156 million distinct nanostructures comprised of Ru, Co, Mn, and Cr to find alternatives to Ir catalysts for OER. Over 40 RuCoMnCr oxides, ranging from low to high activity, were selected, scaled to milligram levels, and studied for their catalytic performance. The activities measured within the megalibrary closely correlated (r = 0.84) with those of the macroscopic samples. In a PEMWE, the most active catalyst, Ru52Co33Mn9Cr6 oxide, demonstrated a voltage of 1.58 V at 1 A/cm2 and 1.77 V at 3 A/cm2. At 1 A/cm2, it operated continuously for over 1000 h with an average voltage increase rate of 57 μV/h. This study establishes a roadmap to accelerate catalyst discovery for energy conversion, and the platform is a route to large data sets that will facilitate the development of AI and machine learning algorithms that can identify key catalyst design features.
