軽量マグネシウム合金の強度向上に寄与する双晶形成の3D初観察(First 3D look at strength-boosting ‘twinning’ behavior in lightweight magnesium alloy)

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2025-08-07 ミシガン大学

ミシガン大学の研究チームは、軽量マグネシウム合金における強度向上メカニズム「ツイン(二重晶)形成」を世界で初めて3D X線イメージングで可視化した(Science誌)。小型CTで結晶粒配向を特定後、欧州放射光施設のダークフィールドX線顕微鏡で異なる応力条件下の結晶構造変化を観察。その結果、二重晶は必ず三晶接合点に形成され、ツイン境界が他の結晶粒と接する箇所には欠陥が蓄積しやすいことが判明した。これらの知見は、延性向上と欠陥蓄積の両面からマグネシウム合金設計に重要であり、自動車の軽量化や燃費向上への応用が期待される。

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マグネシウムにおける変形双晶の三次元核生成と成長 Three-dimensional nucleation and growth of deformation twins in magnesium

Sangwon Lee, Michael Pilipchuk, Can Yildirim, Duncan Greeley, […] , and Ashley Bucsek
Science  Published:7 Aug 2025
DOI:https://doi.org/10.1126/science.adv3460

Editor’s summary

Dark-field x-ray microscopy has revealed the three-dimensional details of deformation twinning inside an embedded grain in a bulk, polycrystalline magnesium-aluminum alloy. Lee et al. studied twinning in these lightweight alloys because twins can both accommodate plastic strain and serve as unwanted crack initiation sites. Under applied stress, twins appeared as irregular ellipsoid shapes. The authors studied preferential growth directions and how twinning relates to dislocation accumulation that precedes crack initiation. —Phil Szuromi

Abstract

At two-thirds the weight of aluminum, magnesium alloys have the potential to reduce the fuel consumption of transportation vehicles. These advancements depend on our ability to optimize the desirable versus undesirable effects of deformation twins, which are three-dimensional (3D) microstructural domains that form under mechanical stresses. Previously only characterized through surface or thin-film measurements, we present 3D in situ characterization of deformation twinning inside an embedded grain over mesoscopic fields of view using dark-field x-ray microscopy supported by crystal plasticity finite element analysis. The results revealed the role of triple junctions on twin nucleation and the sequence and irregularity of twin growth and showed that twin-grain junctions, twin-twin junctions, and twin boundaries were the sites of localized dislocation accumulation.

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