2025-06-27 東京科学大学
図1．制御／リビングクリック重合のイメージ図
＜関連情報＞
- https://www.isct.ac.jp/ja/news/n81uhh4xsuz1
- https://www.isct.ac.jp/plugins/cms/component_download_file.php?type=2&pageId=&contentsId=1&contentsDataId=1845&prevId=&key=14639599dfdbf867202532e0fb683a8d.pdf
- https://pubs.acs.org/doi/10.1021/jacs.5c01247
重付加反応中に双方向の連鎖成長が可能な制御された「リビング」クリック重合 Controlled/″Living″ Click Polymerization with Possible Bidirectional Chain-Growth Propagation during Polyaddition
Satoshi Sakai,Takuya Nakamura,Seiichiro Uchida,Yuto Nakauchi,Mineto Uchiyama,Tomohiro Kubo,Masami Kamigaito,and Kotaro Satoh
Journal of the American Chemical Society Published: June 13, 2025
DOI:https://doi.org/10.1021/jacs.5c01247
Abstract
In this work, we found a new class of controlled/″living″ polymerization system, which proceeds bidirectional fashion using click reaction of AB monomer bearing azide and alkyne functionalities in a single molecule. The click polymerization of the AB monomer proceeded well using both azide and alkyne initiators in a well-controlled manner in either growth direction to afford polymers with predetermined molecular weights and narrow molecular weight distributions, as well as the terminal structures inherited from the initiator. Especially, the polymerizations with the difunctional initiators provided well-defined linear polymers with azide or alkyne groups at both termini. This approach also allows for polymerization control over the second monomer to give a block copolymer.
