反強誘電体における分極トポロジーと構造トポロジーの強い相互作用を発見 (Strong Interplay Found Between Polar and Structural Topologies in Antiferroelectrics)

2026-03-16 中国科学院(CAS)

反強誘電体における新たなトポロジー構造の形成機構を解明した研究。従来は高いエネルギー障壁により分極回転が困難とされていたが、中国科学院金属研究所などの研究チームは結晶中の転位欠陥に着目。PbZrO3薄膜の転位コアが分極の収束点となり、周期的ひずみ場と電気双極子の相互作用によって「アンチヘッジホッグ」型の分極トポロジーが自発形成されることを確認した。さらに、電歪効果やフレキソ電気効果により局所電場が生じ、分極の再配向を誘起する仕組みを解明。この成果は、反強誘電体における欠陥工学を活用したトポロジー設計と高密度メモリ応用への道を開く。

反強誘電体における分極トポロジーと構造トポロジーの強い相互作用を発見 (Strong Interplay Found Between Polar and Structural Topologies in Antiferroelectrics)
Characterization of atomic composition at interfacial dislocation cores and piezoelectric properties of the antiferroelectric PbZrO3 thin film. (Image by IMR)

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極性トポロジーと構造トポロジー間の強い相互作用 Strong interplay between polar and structural topologies

Ru-Jian Jiang,Mei-Xiong Zhu,Su-Zhen Liu,Yu-Ting Chen,Desheng Ma,Yan-Peng Feng,Min-Jie Zou,Meng-Jiao Han,Chi Hou Lei,Yu-Jia Wang,Yun-Long Tang,Yin-Lian Zhu & Xiu-Liang Ma
Nature Communications  Published:13 March 2026
DOI:https://doi.org/10.1038/s41467-026-70515-y  Unedited version

Abstract

Topological structures in condensed matter systems unlock new possibilities for the development of nanoelectronic devices. However, the potential of antiferroelectrics to host topological features remains largely unexplored, constrained by significant energy barriers from antiparallel dipole coupling that suppress polarization rotation and challenges in high-quality film fabrication. Here for the first time, we find that, dislocations, the most common one-dimensional topological structures in crystals, exhibit unexpectedly strong couplings with polar topologies and induce ordered polar antihedgehog lattices in antiferroelectric PbZrO3 driven by the interplay of electrostrictive effect and the flexoelectric field. Combined atomic-resolution transmission electron microscopy and phase-field simulations, it is revealed that the polarizations converging at dislocation cores and diverging between dislocations define lattices characterized by checkerboard-like antihedgehogs, respectively. Unexpected interplay between polar and structural topologies establishes a new paradigm for topology design.

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