半導体物理学:ポーラロン形成を初めて観測(Semiconductor physics: polaron formation observed for first time)

2026-02-11 ミュンヘン大学(LMU)

ミュンヘン大学(LMU)の研究チームは、半導体中でキャリアが格子振動と結合して形成される「ポーラロン」の生成過程を初めて時間分解で直接観測した。超高速分光法を用いて、光励起直後に電子とフォノンが相互作用し、数フェムト秒からピコ秒スケールで準粒子が形成される様子を捉えた。これにより、電荷輸送やエネルギー緩和を左右する基本機構の理解が進展。結果は半導体物性や次世代電子・光デバイス設計に重要な知見を与えるもので、量子材料研究の発展にも寄与する。

Their study is “of great value for the scientific community and will help both in the planning of further experiments and in the development of various devices.”, says LMU-physicist Jochen Feldmann. The measured distribution of electrons at time zero can be seen on the screen. © Jan Greune / LMU

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BiOIナノプレートレットにおけるフレーリッヒポーラロン形成の直接観察 Direct observation of Fröhlich polaron formation in BiOI nanoplatelets

Matthias F. Kestler, Kyung Chul Woo, Justin W. X. Lim, Lucas M. Prins, Jochen Feldmann, and Zhi-Heng Loh
Physical Review Materials  Published: 11 February, 2026
DOI: https://doi.org/10.1103/wcq2-gpmz

Abstract

For large polarons, Fröhlich theoretically derived an increased effective mass and a decreased energy as compared to free charge carriers. These changes have hitherto eluded direct observation. Here, we report on the direct observation of large polaron formation after photoexcitation in BiOI nanoplatelets, a system known to host spatially separated e-h pairs. We employ time- and momentum-resolved photoemission electron microscopy with 50-fs pulses to monitor the dynamics of the conduction-band (CB) dispersion ⁡(). Indeed, we observe a doubling of the effective mass accompanied by a decrease of the CB energy leading to an overall drop of 160 meV.

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