樹皮資源を活用した高バイオマス複合材料の開発~力学特性に基づく生分解評価手法を確立~

2026-01-29 東北大学

東北大学大学院環境科学研究科の研究グループは、未利用の樹皮資源を60wt.%含有する高バイオマス複合材料を開発し、その生分解挙動を力学特性から定量評価する新手法を確立しました。コンポストおよび屋外土壌環境下での試験により、材料の引張強さの低下と生分解度の間に指数関係が成立することを実証し、分子鎖切断理論に基づく力学―生分解連成モデルを初めて定式化しました。また、本材料は分解初期には十分な電気絶縁性能を維持することから、一定期間機能した後に分解する生分解性エレクトロニクス材料としての可能性も示されました。本研究は、生分解性材料を「どの程度分解したか」だけでなく、「いつまで機能するか」という観点から評価・設計する新たな指針を提示し、資源循環型材料開発や環境負荷低減に貢献する成果です。

樹皮資源を活用した高バイオマス複合材料の開発~力学特性に基づく生分解評価手法を確立~
図1. 樹皮−PBS複合材料の作製と構造。(a)粉砕した複合材料ペレットの外観、(b)引張試験に用いたダンベル形試験片の寸法および試験片外観、(c)作製した複合材料断面のデジタル顕微鏡像。

<関連情報>

樹皮をベースとしたグリーン複合材料の引張特性による生分解性の評価と解釈 Evaluating and interpreting biodegradability of a tree bark–based green composite through tensile properties

Lovisa Rova,Zhenjin Wang,Hiroki Kurita & Fumio Narita
npj Materials Degradation  Published:20 January 2026
DOI:https://doi.org/10.1038/s41529-026-00740-9 An unedited version of this manuscript

Abstract

This study is about the fabrication and evaluation of a new green composite made from the tree bark of the Yakushima Jisugi tree and polybutylene succinate (PBS) polymer. The tensile properties and biodegradability of the composite were evaluated, including a 6-month-long soil burial test. The tensile strength of the composite was not as high as that of neat PBS since the bark content was high at 60 wt.%. In compost, the composite degraded by about 13% in 8 weeks. The composite also displayed biodegradability in outdoor soil, which was evaluated by measuring changes in tensile and thermal properties. The tensile modulus, strength, and elongation at break deteriorated, and the melting point decreased as soil burial progressed, eventually reaching a melting point 2 °C lower than the as-fabricated specimen after 30 weeks of burial. Furthermore, by combining the tensile data from the biodegradation experiments in compost and soil, it was estimated that the composite degraded by about 5% during 30 weeks of soil burial. A theoretical framework based on random chain-scission kinetics was introduced to rationalize the experimentally observed exponential relationship between increased degree of biodegradation and decrease in tensile strength, providing a description of tensile strength deterioration as a function of material degradation. Due to the material’s excellent biodegradability, it has potential applications in agriculture and as a component in time-programmed devices that self-disintegrate after being discarded. In addition, partial discharge testing revealed that the composite exhibited sufficient initial dielectric strength, further supporting its potential for transient applications such as biodegradable sensors or disposable electronic packaging.

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