油を 0.5%で固める単結晶を特定!~新技術で安定な油のゲルの作製へ~

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2025-06-25 広島大学

広島大学などの研究チームは、植物油をゲル化する際に形成される繊維状結晶が「脂質ウィスカー結晶」という単結晶であることを、透過型電子顕微鏡と電子回折解析で世界で初めて確認しました。この結晶は機械的強度と安定性に優れ、わずか0.5wt%の低濃度でも油を安定してゲル化可能です。温度制御によりその特性はさらに向上し、4ヶ月の保存でも油漏れしません。本技術は植物性代替肉の風味・食感の改善に貢献する可能性があります。

油を 0.5%で固める単結晶を特定!~新技術で安定な油のゲルの作製へ~
図1:オレオゲル中の脂質ウィスカー結晶

<関連情報>

安定なオレオゲル調製のための脂質ウィスカー結晶の生成 Creation of lipid whisker crystals for stable oleogel preparation

Haruhiko Koizumi, Fumiya Nakano, Noritaka Oishi, Tomoya Yamazaki, Yuki Kimura, Shinji Tsuda, Satoru Ueno
Food Research International  Available online: 5 May 2025
DOI:https://doi.org/10.1016/j.foodres.2025.116451

Highlights

  • Elongated fibrous crystals were lipid whisker crystals.
  • Lipid whisker crystals improves the stability of the oleogel.
  • Oleogels composed of lipid whisker crystals exhibited high mechanical strength.
  • Lipid whisker crystals grew by elongation of the (011) crystallographic face.

Abstract

The development of a novel manufacturing technology of oleogels is important for overcoming the serious problem of inadequate “juiciness” of plant-based meats. We have recently demonstrated that gelation occurs with the addition of only 0.5 wt% fully hydrogenated hard palm mid-fraction (FHHPMF), which forms elongated fibrous crystals in oleogels. In this paper, we reveal from the observation of a spot-like diffraction pattern using transmission electron microscopy (TEM) that elongated fibrous crystals are single crystals, i.e., lipid whisker crystals. In addition, we show through analysis of electron diffraction patterns that lipid whisker crystals are grown by elongation in the (011) crystallographic face. We also observed that such oleogels composed of lipid whisker crystals exhibit high mechanical strength and stability. These results suggest that the oleogels composed of lipid whisker crystals have strong potential to advance the technology of plant-based meats.

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