2025-10-13 アイルランド・リムリック大学（UL）
＜関連情報＞
- https://www.ul.ie/news/worlds-first-full-cell-dual-cation-battery-developed-at-university-of-limerick
- https://www.sciencedirect.com/science/article/pii/S221128552500802X
高容量、長寿命、デュアルアルカリイオン電池のための相乗的なLi-Na共合金化 Synergistic Li-Na co-alloying for high-capacity, long-life, dual-alkali ion batteries
Syed Abdul Ahad, Christopher Owen, Niraj Nitish Patil, Temilade Esther Adegoke, Clive Downing, Kevin M. Ryan, Shalini Singh, Andrew J. Morris, Hugh Geaney
Nano Energy Available online 4 September 2025
DOI:https://doi.org/10.1016/j.nanoen.2025.111443
Graphical Abstract
Highlights
- Identification of a synergistic Na and Li alloying mechanism in Ge, that delivers a twofold enhancement in capacity (605 mAh g⁻¹) compared to Na only.
- Mechanistic insight via electrochemical, structural, and computational (AIRSS) analysis, revealing a previously unreported LiNaGe₃ phase.
- The first dual-ion electrolyte strategy to enhance performance of an alloying-mode anode in a full-cell configuration.
- Demonstration of a novel and scalable chemical amorphization protocol for alloying anodes, bypassing Li-ion pre-cycling.
Abstract
High-capacity, alloying-mode sodium-ion battery (NIB) anode materials remain elusive, mostly due to poor Na ion diffusivity within attractive candidates such as Ge and Si. Herein, for the first time, increased cation activity is unlocked in a Ge nanowire active material, through the use of a dual ion Li/Na electrolyte. In comparison to low specific capacity (297 mAh g−1) in the Na-only electrolyte, the dual electrolyte enabled a 2x capacity increase (605 mAh g−1) via a dual-cation alloying mechanism which has never been reported before. Electrochemical data and material characterization demonstrates that the mechanism follows an amorphous path, with the formation of amorphous Na-rich and Li-rich Ge phases during electrochemical alloying reactions. Complex stoichiometries of Li-Na-Ge ternary phases were validated using ab-initio random structure searching (AIRSS) computational technique. This dual-cation mechanism led to exceptional specific capacity (80 % capacity retention after 1000 cycles at 1 mA cm−2), with demonstrated full-cell compatibility using a sustainable FeS2 cathode.
