中国の研究者が多機能で環境に優しい空気ろ過素材を開発(Researchers Develop Eco-Friendly, Multifunctional Air Filtration Materials)

2025-08-22 中国科学院(CAS)

中国科学院・新疆理化技術研究所の研究チームは、産業現場向けに環境負荷の少ない高機能エアフィルター材料を開発した。従来のセルロース紙ベースのフィルターは強度や耐久性に乏しく、粉塵や有害ガス除去を同時に満たすことが難しかった。研究チームは、再生可能資源由来のLyocell繊維と耐熱性に優れる玄武岩繊維を、接着剤を使わずウェットレイド法で複合化。これにより柔軟性を保ちながら破裂強度・引裂強度を大幅に改善した。さらに、繊維表面に金属有機構造体ZIF-8をその場成長させ、微粒子や有害ガスを効率的に吸着できる機能を付与した。試験では、250℃の高温環境下でも安定したろ過性能を維持し、従来材料を大きく上回る性能を示した。この成果は石炭化学、石油精製、半導体製造など高温・高負荷環境下における持続可能な空気浄化ソリューションとして期待される。

<関連情報>

高性能空気濾過用高柔軟性・多機能性リヨセル-玄武岩繊維濾材 Highly flexible and multifunctional lyocell-basalt fiber filter media for high-performance air filtration

Ze-Xin Chen, Desalegn Atalie, Hui Li, Ming-Cheng Gao, Peng-Cheng Ma
Journal of Hazardous Materials  Available online: 11 July 2025
DOI:https://doi.org/10.1016/j.jhazmat.2025.139221

Graphical Abstract

中国の研究者が多機能で環境に優しい空気ろ過素材を開発(Researchers Develop Eco-Friendly, Multifunctional Air Filtration Materials)

Highlights

  • Highly flexible and robust filter prepared from lyocell and basalt fiber (LC/BF).
  • High filtration (97.7 %) achieved for PM0.3 and with effective SO2 adsorption.
  • BF improved heat resistance, bursting (by 136.5 %), and tear strength (by 128.9 %).
  • The filter had better breathability, thermal stability, and antibacterial properties.
  • LC/BF-ZIF-8 filters are the best candidate for fine PM and pollutant removal.

Abstract

Cellulose-based functionalized fabrics are emerging as promising air purification filter materials. However, limitations such as poor moisture resistance, low strength, and heat sensitivity are challenging in the practical application of fine particulate matter filtration. Here, we developed a flexible and multifunctional lyocell/basalt fiber (LC/BF) filter fabric using a wet-laid process, avoiding the need for additional binders. The filter fabric was further enhanced with ZIF-8 functionalization to achieve considerable PM0.3 and sulfur dioxide removal. The incorporation of LC fibrillated nanofibers significantly improved the fabric’s flexibility, light weight, and filtration performance. The addition of BF reduced pressure drops and significantly increased burst (136.5 %) and tear strength (128.9 %) compared to the pure LC filter media. The BF also helps improve moisture (55.8 %), thermal, and chemical resistance. The resulting LC/BF-25@ZIF-8 fabric demonstrated a remarkable filtration efficiency of 97.72 % for PM0.3 particles. This functionalization also led to significant enhancements in gas adsorption, specifically 93 % improvement for SO2 and 111.5 % for the volatile organic compound methylbenzene adsorption, showcasing synergetic simultaneous capture capabilities. Furthermore, excellent antibacterial activity against E. coli, S. aureus, and S. pneumoniae was obtained, with inhibition rates exceeding 99.8–99.9 %. This eco-friendly approach, combining the distinctive properties of LC/BF and ZIF-8, offers a promising solution for multifunctional advanced air filtration applications, such as fitting into sophisticated equipment, combined gas adsorption, and environmental tolerance.

1104空気調和
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