燃料電池用の高性能鉄系触媒を中国の研究チームが開発（Chinese Scientists Develop High-Performance Iron Catalyst for Fuel Cells）

2025-08-26 中国科学院（CAS）

Construction of CS Fe/N-C (Image by ZHAO Yasong)

＜関連情報＞

• https://english.cas.cn/newsroom/research_news/chem/202508/t20250820_1051107.shtml
• https://www.nature.com/articles/s41586-025-09364-6

曲面担体上の単原子Fe触媒による酸性酸素還元反応 Acidic oxygen reduction by single-atom Fe catalysts on curved supports

Yasong Zhao,Jiawei Wan,Chongyi Ling,Yanlei Wang,Hongyan He,Nailiang Yang,Rui Wen,Qinghua Zhang,Lin Gu,Bolong Yang,Zhonghua Xiang,Chen Chen,Jinlan Wang,Xin Wang,Yucheng Wang,Huabing Tao,Xuning Li,Bin Liu,Suojiang Zhang & Dan Wang
Nature  Published:13 August 2025
DOI:https://doi.org/10.1038/s41586-025-09364-6

Abstract

Developing highly active and durable electrocatalysts for cost-effective proton-exchange membrane fuel cells is challenging^1,2,3. Fe/N–C catalysts are among the most promising alternatives to the platinum group metal catalysts, but their activity and durability still cannot meet the performance criteria due to the strong adsorption of oxygenated reaction intermediates and the demetallization of Fe species caused by the Fenton reaction^4,5,6,7,8. Here we design and develop a new type of Fe/N–C catalyst that is composed of numerous nanoprotrusions dispersed on two-dimensional carbon layers with single Fe-atom sites primarily embedded within the inner curved surface of the nanoprotrusions. The graphitized outer carbon layer of the nanoprotrusions can not only effectively weaken the binding strength of the oxygenated reaction intermediates, but also reduce the hydroxyl radical production rate. As a result, the Fe/N–C catalyst delivers one of the best-performing platinum group metal-free proton-exchange membrane fuel cell performances, achieving a record high power density of 0.75 W cm⁻² under 1.0 bar H₂–air with 86% activity retention after more than 300 hours of continuous operation.