トポロジー分野のブレイクスルー:Chern絶縁体における非相互クーロン抗力 (Topological Breakthrough: Non-Reciprocal Coulomb Drag in Chern Insulators)

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2025-04-24 北京大学(PKU)

トポロジー分野のブレイクスルー:Chern絶縁体における非相互クーロン抗力 (Topological Breakthrough: Non-Reciprocal Coulomb Drag in Chern Insulators)
Figure 1. Non-reciprocity of longitudinal and transverse Coulomb drag. (a–e) Circuit setups for longitudinal drag; (f–j) data at 20 mK. (k–m) Setups for transverse drag; (n–p) corresponding measurements.

北京大学の研究チームは、リチウムイオン電池向けの新しい固体電解質材料として、コハク酸ジニトリル(SN)とリチウム塩の混合物に注目し、その溶媒和構造と動態を詳細に解析しました。この研究では、超高速振動分光法と密度汎関数理論(DFT)計算を用いて、プラスチック結晶相(22℃)および液体相(80℃)におけるLi⁺の配位数が、それぞれ約2および2.5〜3であることを明らかにしました。特に、80℃の条件下で0.5 mol/kgのLiBF₄–SN溶液では約60%、LiClO₄–SN溶液では約90%の塩が解離し、Li⁺がSN分子と安定に結合していることが示されました。このような詳細な溶媒和構造の理解は、リチウムイオン電池の性能向上に寄与する新しい固体電解質の設計に重要な知見を提供します。

<関連情報>

チェルン絶縁体間の非相反クーロン抗力 Non-reciprocal Coulomb drag between Chern insulators

Yu Fu,Yu Huang & Qing Lin He
Nature Communications  Published:29 March 2025
DOI:https://doi.org/10.1038/s41467-025-58401-5

Abstract

Coulomb interaction between two closely spaced but electrically isolated conductors can induce a voltage in one of them upon feeding a current into the other. This effect has been widely studied in nonmagnetic strongly interacting systems and historically interpreted in terms of momentum and energy exchanges, which thus complies with Onsager’s reciprocity. Here we report the non-reciprocal Coulomb drag observed between two ferromagnetic Chern insulators that host quantum anomalous Hall effects. By measurements with current and circuit reversals, we discovered strong drag signals in both the longitudinal and transverse directions which violate Onsager’s reciprocity. These drag signals only emerge when the Chern insulator is in a multidomain state. Combined with the nonlinear IV characteristics and power-law temperature dependence, this drag is attributed to the rectifications of mesoscopic fluctuations and quantum shot noise as well as the current cumulant. The drag signals are accompanied by strong magnetic fluctuations, highlighting the role played by magnetic dynamics. The present study expands the Coulomb drag to the realm of magnetic topological systems.

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