反強磁性準結晶の存在を初めて明らかに! ~周期を持たない長距離反強磁性秩序を発見~

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2025-04-11 東京理科大学,東北大学,Australian Nuclear Science and Technology Organisation,科学技術振興機構

東京理科大学先進工学部の田村隆治教授らの研究グループは、東北大学などと共同で、世界で初めて反強磁性を示す正二十面体準結晶(Au₅₆In₂₈.₅Eu₁₅.₅)の存在を実証した。準結晶は非周期的な原子配列を持ち、これまで長距離磁気秩序の存在は未確認だったが、6.5Kでの反強磁性転移と中性子回折による磁気ブラッグ反射の観測により立証された。この発見は、準周期的磁気秩序の理解を深め、スピントロニクスや磁気冷却への応用が期待される。

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準結晶における反強磁性秩序の観測 Observation of antiferromagnetic order in a quasicrystal

R. Tamura,T. Abe,S. Yoshida,Y. Shimozaki,S. Suzuki,A. Ishikawa,F. Labib,M. Avdeev,K. Kinjo,K. Nawa & T. J. Sato
Nature Physics  Published:14 April 2025
DOI:https://doi.org/10.1038/s41567-025-02858-0

反強磁性準結晶の存在を初めて明らかに! ~周期を持たない長距離反強磁性秩序を発見~

Abstract

Quasicrystals are long-range-ordered materials with atypical rotational symmetries, such as 5-fold, 10-fold or 12-fold symmetries, which are incompatible with crystallographic periodicity. Although spin-glass-like freezing phenomena have been observed in quasicrystals, antiferromagnetic order has not. Here we report experimental evidence for antiferromagnetic order in the icosahedral quasicrystal Au56In28.5Eu15.5. Its magnetization curve shows a sharp cusp at a Néel temperature of 6.5 K, and both metamagnetic anomaly below and specific heat anomaly at this temperature are consistent with an antiferromagnetic transition. The appearance of magnetic Bragg reflections in the neutron diffraction data below the Néel temperature further confirms the long-range antiferromagnetic order in this icosahedral quasicrystal. Our discovery resolves the long-standing issue of whether antiferromagnetic order is possible in real quasicrystals, inviting further studies particularly on antiferromagnetic icosahedral quasicrystals and quasiperiodic magnetic order, as opposed to periodic magnetic order generally in condensed-matter physics.

1700応用理学一般
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