2024-10-04 ペンシルベニア州立大学(PennState)
＜関連情報＞
- https://www.psu.edu/news/materials-research-institute/story/revamping-old-technique-see-battery-design-new-way
- https://pubs.acs.org/doi/10.1021/jacs.4c03791
電池の界面構造と電気化学的挙動を高分解能電気キャピラリティで結びつける Linking Interfacial Structure and Electrochemical Behaviors of Batteries by High-Resolution Electrocapillarity
Jianwei Lai,Hanrui Zhang,Kang Xu,Feifei Shi
Journal of the American Chemical Society Published: July 16, 2024
DOI:https://doi.org/10.1021/jacs.4c03791
Abstract
The electrode–electrolyte interface governs the kinetics and reversibility of all electrochemical processes. While theoretical models can calculate and simulate the structure and associated properties of this intriguing component, their validation by direct experimental measurement has been a long-standing challenge. Electrocapillarity is a classical technique that derives the interfacial structure through potential-dependent surface tensions, but its limited resolution has confined its application to ideal systems such as extremely diluted aqueous electrolytes. In this work, we revive this technique with unprecedented time resolution, which allows fast and precise extraction of intrinsic interfacial structure and properties for a wide spectrum of electrolytes, be it ideal or nonideal, aqueous or nonaqueous, dilute or superconcentrated. For the very first time, this new electrocapillarity enables the measurements of a set of interfacial quantities, such as ion concentration distribution and potential drop across Helmholtz planes. Applying it on Zn-battery electrolytes, we discovered that Cl– specific adsorption at the inner-Helmholtz plane results in unexpected Zn2+ aggregation at the outer-Helmholtz plane, and identified such a unique interfacial structure as the fundamental driving force for fast Zn deposition/stripping kinetics and crystallographic texturing. The renaissance of electrocapillarity brings a new tool to the understanding and design of new electrolytes for future battery systems.
