コバルトは珪酸塩鉱物鉱石の低水炭酸化を遅らせる(Cobalt Slows the Low-Water Carbonation of Silicate Mineral Ores)

2025-01-09 パシフィック・ノースウェスト国立研究所(PNNL)

＜関連情報＞

• https://www.pnnl.gov/publications/cobalt-slows-low-water-carbonation-silicate-mineral-ores
• https://pubs.rsc.org/en/Content/ArticleLanding/2024/CP/D4CP02092H

コバルト置換が低水超臨界二酸化炭素中のフォルステライト炭酸化を遅らせる Cobalt substitution slows forsterite carbonation in low-water supercritical carbon dioxide

John S. Loring, Tenley E. Webb, Mark E. Bowden, Mark H. Engelhard and  Sebastien N. Kerisit
Physical Chemistry Chemical Physics  Published:09 Oct 2024
DOI:https://doi.org/10.1039/D4CP02092H

Abstract

Cobalt recovery from low-grade mafic and ultramafic ores could be economically viable if combined with CO₂ storage under low-water conditions, but the impact of Co on metal silicate carbonation and the fate of Co during the carbonation reaction must be understood. In this study, in situ infrared spectroscopy was used to investigate the carbonation of Co-doped forsterite ((Mg,Co)₂SiO₄) in thin water films in humidified supercritical CO₂ at 50 °C and 90 bar. Rates of carbonation of Co-doped forsterite to Co-rich magnesite ((Mg,Co)CO₃) increased with water film thickness but were at least 10 times smaller than previously measured for pure forsterite at similar conditions. We suggest that the smaller rates are due to thermodynamic drivers that cause water films on Co-doped forsterite to be much less oversaturated with respect to Co-doped magnesite, compared to the pure minerals.