地下水中PFASを捕捉する新手法を開発(University of Minnesota researchers partner on new method to trap PFAS in groundwater)

2026-01-13 ミネソタ大学

ミネソタ大学(University of Minnesota)を中心とする研究チームは、地下水に広く汚染物質として存在する PFAS(ペルフルオロアルキル化合物・「フォーエバーケミカルズ」) を効率的に捕捉する 新しい地中処理法 を開発・実証した。PFAS は炭素‐フッ素結合が極めて強く、従来の浄化技術での除去が困難とされてきたが、研究では 特殊に設計した超微細な炭素材料(コロイダルカーボン製品:CCP) を地下に注入することで、PFAS を物理的に捉えるフィルターゾーンを形成する。実験では、現場試験において PFAS 濃度が最大で 4 桁低下し、検出限界以下に達する例も確認 された。CCP 法は長鎖・短鎖両方の PFAS に有効であり、従来法と比較して 運用コストを大幅に低減できる可能性 が示された。論文は The Journal of Hazardous Materials に掲載され、実際の地下水環境での実装可能性が確認された。長期的な維持能力や異なる土壌条件下での性能評価が今後の課題として挙げられている。
<関連情報>

パーフルオロアルキル化合物およびポリフルオロアルキル化合物(PFAS)に汚染された地下水の原位置処理のためのポリマー安定化活性炭の現場実証 Toward a sustainable energy future using ammonia as an energy carrier: global supply chain cost and greenhouse gas emissions

James Hatton, Peng-Fei Yan, Chen Liu, Suna Jo, Jovan Popovic, Benjamin L. Rhiner, Joseph Wong, Micala Mitchek, Jiaqi Li, William A. Arnold, Matt F. Simcik, Kurt D. Pennell
Journal of Hazardous Materials  Available online: 28 October 2025
DOI:https://doi.org/10.1016/j.jhazmat.2025.140292

Graphical Abstract

地下水中PFASを捕捉する新手法を開発(University of Minnesota researchers partner on new method to trap PFAS in groundwater)

Highlights

  • Laboratory aquifer cell test demonstrated the potential of an injectable sorbent (CCP).
  • A push-pull CCP field test was conducted for in situ treatment of PFAS-impacted groundwater.
  • PFAS concentrations were reduced by up to 4 orders-of-magnitude at 10-months post-injection.
  • CCP treatment has much lower long-term operation costs than a “pump-and-treat” system.

Abstract

In situ remediation of groundwater impacted by per- and polyfluoroalkyl substances (PFAS) is challenging due to their resistance to destructive processes and the need to meet part-per-trillion (ng/L) drinking water standards. This study involved a field demonstration of a polymer-stabilized activated carbon (hereafter referred to as colloidal carbon product-CCP) using a “push-pull” test, consisting of a “push” phase (CCP injection) and a “pull” phase (withdrawal of treated groundwater), to assess the effectiveness of the treatment technology. A laboratory-scale aquifer cell experiment using site aquifer materials and simulated groundwater demonstrated 90.9 to > 99.9% removal of all six tested PFAS by CCP injection. For the field-scale test, a total of 1900-L CCP was injected into a 2.4-meter interval, and 4750 L of water were extracted from the treated interval, with extractions conducted at 3- and 10-months post-injection. Concentrations of PFAS were reduced by up to four orders-of-magnitude, from > 50,000 ng/L total PFAS to below individual detection limits in samples collected 10 months post-injection. An economic analysis indicates that operating costs of the CCP system would be less than half of a comparable “pump-and-treat” system. These findings demonstrate that CCP injection is a practical, efficient, and cost-effective in situ remediation strategy for addressing PFAS-impacted groundwater plumes.

1102水質管理
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